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Chemistry

Saponification value calculator

Determines a fat or oil’s saponification value from a KOH back-titration with HCl.

What this calculator does

Saponification value works out determines a fat or oil’s saponification value from a KOH back-titration with HCl. Enter your own figures above and the answer updates as you type: nothing is fixed in the code, so the result reflects exactly the numbers you supply.

The formula this calculator evaluates is printed under the tool and explained below, so you can check the working by hand or reuse it in a spreadsheet.

The formula

FormulaSV = (Vblank − Vsample) × M(HCl) × 56.1 / sample weight, where 56.1 g/mol is the molar mass of KOH

The inputs explained

FieldWhat to enter
Blank titration volume (mL)A number, measured in mL. Starts at 25.
Sample titration volume (mL)A number, measured in mL. Starts at 18.
Molarity of HCl (mol/L)A number, measured in mol/L. Starts at 0.5.
Sample weight (g)A number, measured in g. Starts at 2.

Worked examples

Every figure in the tables below is produced by this page’s own calculator at build time, so the numbers and the tool always agree. Select any row to load that scenario.

How the answer changes with blank titration volume

Every other input is held at the calculator’s starting values while blank titration volume varies. Select any row to load that scenario into the calculator.

How the answer changes with blank titration volume
Blank titration volume (mL)Saponification valueVolume differenceSample weight used
12.5-77.14 mg KOH/g-5.50 mL2.000 g
18.7510.52 mg KOH/g0.75 mL2.000 g
2598.18 mg KOH/g7.00 mL2.000 g
37.5273.49 mg KOH/g19.50 mL2.000 g
50448.80 mg KOH/g32.00 mL2.000 g
75799.43 mg KOH/g57.00 mL2.000 g